Organozinc reagents are less reactive than Grignard reagents but theyare much more chemoselective. Since theNegishi cross-coupling reaction developed by Ei-ichi Negishi, who was awarded the Nobel Price in chemistry in 2010, a number of cross-coupling reactions involving organozinc derivatives and transition metal catalysts (Pd, Ni, Fe, Co, Cu, ) has been tuned up to form C-C bonds. This book on "Organozinc derivatives and transition metal catalysts" has beenwritten by experts in the field and is a complement to the book entitled "Grignard reagents and transition metal catalysts" (a De Gruyter book, edited by J. Cossy).
Grignard reagents or organozinc reagents, that is the question? From a given substrate, what is the best organometallicreagent and the best transition metal to form a C-C bond by using a cross-coupling reaction? The solution might be found in these two books.
Janine Cossy
is Professor of Organic Chemistry at the ESPCI Paris since 1990. Her research interests focus on the synthesis of natural products and/or biologically active compounds as well as on the development of synthetic methods.
Schlagwörter zu:
Organozinc Derivatives and Transition Metal Catalysts von Janine Cossy - mit der ISBN: 9783110728941
SCI013010 SCIENCE / Chemistry / Analytic; SCI013030 SCIENCE / Chemistry / Inorganic; SCI013040 SCIENCE / Chemistry / Organic; SCI013060 SCIENCE / Chemistry / Industrial & Technical; TEC009010 Technology & Engineering / Chemical & Biochemical; TEC072000 TECHNOLOGY & ENGINEERING / Pharmaceutical; Catalysis; Cross-coupling Reactions; Katalyse; Organic Chemistry; Organische Chemie; Transition Metal Catalysis., Online-Buchhandlung
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